R2.2 How fast? The rate of chemical change questions for IB Chemistry

169 questions on How fast? The rate of chemical change, written by Augment in the style of IB exam papers. Six of them are below in full, to answer on paper.

  • IB Chemistry
  • Part of R2 How much, how fast and how far?
  • SL and HL

Questions by paper and level

SL and HL questions are for students at either level. HL only questions cover what only HL students study.

PaperSL and HLHL onlyAll
Paper 1A343367
Paper 1B191433
Paper 2333669
Every paper8683169

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Questions to try

Written by Augment in the style of IB exams, not past papers. Answer them on paper, then check each one against its markscheme with a free account.

Question 1 · CHEM-00330Paper 1A · 1 mark

Why is a high activation energy a useful property of a fuel?

  1. A

    It makes the combustion reaction more exothermic.

  2. B

    The fuel does not ignite at room temperature until energy is supplied, for example by a spark.

  3. C

    It increases the energy density of the fuel.

  4. D

    It ensures that the fuel undergoes complete combustion.

Question 2 · CHEM-00987Paper 1B · 6 marks

A student prepared solutions of sodium thiosulfate of different concentrations for a rate experiment by diluting a 0.200 mol dm−3 stock solution with distilled water. The volumes were measured with a 50 cm3 measuring cylinder (± 0.5 cm3).

Mixture

1

2

3

4

5

Volume of stock solution / cm3

50.0

40.0

30.0

20.0

10.0

Volume of water / cm3

0.0

10.0

20.0

30.0

40.0

[Na2S2O3] / mol dm−3

0.200

0.160

0.0800

0.0400

  1. (a)

    Calculate the concentration of sodium thiosulfate in mixture 3.

    1 mark

  2. (b)

    Calculate the amount, in mol, of sodium thiosulfate in mixture 4.

    1 mark

  3. (c)

    The stock solution was made from sodium thiosulfate pentahydrate, Na2S2O3·5H2O. Calculate the mass needed to make 500.0 cm3 of the stock solution.

    2 marks

  4. (d)

    Calculate the percentage uncertainty in the volume of stock solution used for mixture 5.

    1 mark

  5. (e)

    Suggest a change to the apparatus that would reduce the uncertainty in (d).

    1 mark

Question 3 · CHEM-00759Paper 2 · HL only · 8 marks

Iron is a transition element. Finely divided iron is the catalyst in the Haber process for the manufacture of ammonia.

  1. (a)

    State the condensed electron configuration of an iron atom.

    1 mark

  2. (b)

    Deduce the condensed electron configurations of Fe2+ and Fe3+.

    2 marks

  3. (c)

    Explain why iron can form ions with different charges.

    2 marks

  4. (d)

    The melting point of iron is 1538 °C and that of calcium is 842 °C. Explain this difference.

    2 marks

  5. (e)

    State one characteristic property of transition elements, other than catalytic activity, variable oxidation state and high melting point, that is shown by iron.

    1 mark

Question 4 · CHEM-00366Paper 1A · 1 mark

The table gives the potential energy of the reactants, the highest point on the reaction pathway and the products for a reaction.

Point on the energy profile

Potential energy / kJ mol−1

Reactants

150

Highest point (transition state)

230

Products

60

What is the enthalpy change, ΔH, for the reaction, in kJ mol−1?

  1. A

    −170

  2. B

    −90

  3. C

    +80

  4. D

    +90

Question 5 · CHEM-01061Paper 1B · HL only · 10 marks

A student compared metal oxides as catalysts for the decomposition of hydrogen peroxide. 0.50 g of a powdered oxide was added to 25.0 cm3 of 0.50 mol dm−3 hydrogen peroxide in a conical flask connected to a gas syringe. The volume of oxygen collected after 60 s was recorded.

Oxide

Volume of O2 after 60 s / cm3 ± 1 cm3

none

0

manganese(IV) oxide, MnO2

62

lead(IV) oxide, PbO2

47

copper(II) oxide, CuO

9

iron(III) oxide, Fe2O3

4

zinc oxide, ZnO

1

  1. (a)

    Write the equation for the decomposition of hydrogen peroxide.

    1 mark

  2. (b)

    State two variables, other than the mass of oxide, that should be controlled.

    2 marks

  3. (c)

    Calculate the mean rate of oxygen production, in cm3 s−1, with manganese(IV) oxide over the first 60 s.

    1 mark

  4. (d)

    Calculate the maximum volume of oxygen that could be produced, in cm3. Assume the molar volume of a gas under the conditions of the experiment is 24.8 dm3 mol−1.

    2 marks

  5. (e)

    The student concluded that "only oxides of transition elements are effective catalysts for this reaction". Evaluate this conclusion using the data.

    2 marks

  6. (f)

    Outline how the student could show that manganese(IV) oxide is not used up in the reaction.

    1 mark

  7. (g)

    Deduce the oxidation state of manganese in MnO2.

    1 mark

Question 6 · CHEM-00761Paper 2 · HL only · 9 marks

Successive ionization energies of calcium and manganese are shown.

Ionization energy / kJ mol−1

1st

2nd

3rd

4th

5th

Ca

590

1145

4912

6491

8153

Mn

717

1509

3248

4940

6990

  1. (a)

    Deduce the condensed electron configurations of a manganese atom and of the Mn2+ ion.

    2 marks

  2. (b)

    Explain, using the data, why calcium shows only the +2 oxidation state in its compounds while manganese shows several oxidation states.

    2 marks

  3. (c)

    Deduce the oxidation state of manganese in MnO2, K2MnO4 and KMnO4.

    3 marks

  4. (d)

    Manganese(IV) oxide catalyses the decomposition of hydrogen peroxide. Write the equation for this decomposition.

    1 mark

  5. (e)

    Suggest one reason why transition elements and their compounds are often effective catalysts.

    1 mark

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