R1.3 Energy from fuels questions for IB Chemistry

106 questions on Energy from fuels, written by Augment in the style of IB exam papers. Six of them are below in full, to answer on paper.

  • IB Chemistry
  • Part of R1 What drives chemical reactions?
  • SL and HL

Questions by paper and level

SL and HL questions are for students at either level. HL only questions cover what only HL students study.

PaperSL and HLHL onlyAll
Paper 1A33538
Paper 1B11415
Paper 2371653
Every paper8125106

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Questions to try

Written by Augment in the style of IB exams, not past papers. Answer them on paper, then check each one against its markscheme with a free account.

Question 1 · CHEM-00302Paper 1A · 1 mark

Butane, C4H10, is used as a fuel in portable gas stoves. What is the coefficient of oxygen when the equation for the complete combustion of one mole of butane is balanced?

  1. A

    4

  2. B

    5

  3. C

    612

  4. D

    13

Question 2 · CHEM-01120Paper 1B · HL only · 11 marks

A student used a spirit burner to heat 150.0 g of water in a copper can, in order to determine the enthalpy of combustion of ethanol and then use it to find the enthalpy of formation of ethanol.

Measurement

Value

Mass of burner and ethanol before / g ± 0.001 g

45.672

Mass of burner and ethanol after / g ± 0.001 g

45.012

Initial temperature of water / °C ± 0.1 °C

19.8

Final temperature of water / °C ± 0.1 °C

40.5

  1. (a)

    Determine the enthalpy of combustion of ethanol, in kJ mol−1, from these results.

    3 marks

  2. (b)

    Calculate the percentage uncertainty in the value of ΔHc, considering only the mass of ethanol burned and the temperature change.

    2 marks

  3. (c)

    Calculate the percentage error in the value of ΔHc using section 14 of the data booklet.

    1 mark

  4. (d)

    Using your answers to (b) and (c), evaluate whether the difference from the literature value is due mainly to random or to systematic errors, and identify one systematic error.

    2 marks

  5. (e)

    Use the student's value of ΔHc to determine the standard enthalpy change of formation of ethanol, in kJ mol−1, and compare it with the value in section 13 of the data booklet.

    2 marks

  6. (f)

    Suggest why a small percentage error in ΔHc would lead to a much larger percentage error in ΔHf calculated in this way.

    1 mark

Question 3 · CHEM-00557Paper 2 · 7 marks

The standard enthalpies of combustion of four primary alcohols are shown.

Alcohol

Formula

ΔHc∘ / kJ mol−1

methanol

CH3OH

−726

ethanol

C2H5OH

−1367

propan-1-ol

C3H7OH

−2021

butan-1-ol

C4H9OH

−2676

  1. (a)

    Calculate the mean difference in ΔHc∘ between successive members of the series.

    1 mark

  2. (b)

    Explain why ΔHc∘ becomes more negative by an approximately constant amount from one member to the next.

    2 marks

  3. (c)

    Predict ΔHc∘ for pentan-1-ol.

    1 mark

  4. (d)

    Write the equation for the complete combustion of propan-1-ol.

    1 mark

  5. (e)

    Determine the energy released per gram, in kJ g−1, for ethanol and for butan-1-ol, and state which is the better fuel on this basis.

    2 marks

Question 4 · CHEM-00303Paper 1A · 1 mark

Which equation represents the complete combustion of propan-1-ol?

  1. A

    C3H7OH(l)+4O2(g)→3CO2(g)+4H2O(l)

  2. B

    C3H7OH(l)+412O2(g)→3CO2(g)+4H2O(l)

  3. C

    C3H7OH(l)+5O2(g)→3CO2(g)+4H2O(l)

  4. D

    C3H7OH(l)+3O2(g)→3CO(g)+4H2O(l)

Question 5 · CHEM-01122Paper 1B · HL only · 10 marks

A butane gas lighter was used to heat 100.0 g of water in a metal can. The flame was yellow and a layer of soot formed on the bottom of the can.

Measurement

Value

Mass of lighter before / g ± 0.001 g

52.418

Mass of lighter after / g ± 0.001 g

52.168

Initial temperature of water / °C ± 0.1 °C

19.6

Final temperature of water / °C ± 0.1 °C

37.4

  1. (a)

    Calculate the enthalpy of combustion of butane, in kJ mol−1, from these results.

    2 marks

  2. (b)

    Calculate the standard enthalpy change of combustion of butane, in kJ mol−1, using section 13 of the data booklet.

    2 marks

  3. (c)

    Calculate the percentage error in the experimental value, using the section 14 value of −2878 kJ mol−1.

    1 mark

  4. (d)

    Calculate the standard enthalpy change, in kJ mol−1, for the incomplete combustion of butane to carbon monoxide and liquid water, using section 13 of the data booklet.

    2 marks

  5. (e)

    Evaluate whether incomplete combustion alone can explain the experimental result.

    2 marks

  6. (f)

    Suggest why the lighter should be dried and allowed to warm to room temperature before it is reweighed.

    1 mark

Question 6 · CHEM-00796Paper 2 · 7 marks

Propane, C3H8, is the main component of liquefied petroleum gas (LPG). In the gas phase, its complete combustion can be represented as:

C3H8(g)+5O2(g)→3CO2(g)+4H2O(g)
  1. (a)

    Deduce the number of C–H and C–C bonds in one molecule of propane.

    1 mark

  2. (b)

    Calculate the enthalpy change, in kJ mol−1, for this reaction. Use section 12 of the data booklet.

    3 marks

  3. (c)

    The standard enthalpy of combustion of propane is −2219 kJ mol−1. Explain why this value differs from your answer to (b).

    2 marks

  4. (d)

    Using your answer to (b), state whether the products or the reactants are more stable.

    1 mark

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The notes on R1.3 Energy from fuels

More questions in What drives chemical reactions?

  1. R1.1Measuring enthalpy changes
  2. R1.2Energy cycles in reactions
  3. R1.3Energy from fuelsThis page
  4. R1.4Entropy and spontaneityHL only

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